Removal of Cationic Dye from Aqueous Solutions by Modified Acid - Treated Pomegranate Peels (PUNICA GRANATUM): Equilibrium and Kinetic Studies

Authors

  • Mona Abdel Hamid Shouman National Research Center, Physical Chemistry Department
  • Soheir Abdel Atty Khedr National Research Center, Physical Chemistry Department

Keywords:

Pomegranate Peel, Acid – treatment, Adsorption, Thermodynamics

Abstract

In present research, a novel attempt was undertaken to evaluate the effect of various acid – treatments on the adsorption performance of pomegranate peels towards methyl green (MG) dye. The prepared adsorbents were characterized using FTIR, SEM, and BET measurements. A series of experiments were conducted in a batch system to assess the effect of the system variables, i.e. solution pH, temperature, ionic strength and contact time on the adsorption capacity. Maximum adsorption was taken place at pH 5.5 while equilibrium was achieved in 75 min. Equilibrium isotherms were analysed by using Langmuir, Freundlich, Temkin, and Dubinin – Radushkevich isotherm equations. The equilibrium data fitted very well to the Langmuir Isotherm and the maximum capacity reached 29 mg g-1 at 303K. The adsorption kinetics was found to follow pseudo – second – order rate kinetic model. Thermodynamic parameters were also evaluated and revealed that the adsorption process is spontaneous and endothermic in nature.

 

References

Garcia – Montano J, Torrades F,.Perez – Estrada LA, Oller I, Malto S, Maldonado MI, Peral J, "Degredation Pathways of the Commercial Reactive Azodye Procion Red H-E7B under Solar – Assisted Photo – Phenton Reaction", Environmental Science Technology, vol.42, pp. 6663 – 6670, 2008.

Al – Degs YS, El – Barghouthi MI, .Khraisheh MA, Ahmad MN, Allen SJ, " Effect of surface area, micropores, secondary micropores and mesopore volumes of activated carbons on reactive dye adsorption from solution", Seperation Science and Technology, vol.39, pp. 97 – 111, 2004.

Wang S, Boyjoo Y, Choueib A, Zhu H, " Removal of dyes from solution using fly ash and red mud", Water Research, vol.39, pp. 129 – 138, 2005.

Robinson T, McMullan G, Marchant R, Nigam P, " Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative", Bioresource Technology, vol.77, pp. 247 – 255, 2001.

Netpradit S, Thiravetyan P, Towprayoon S, "Adsorption of three azo reactive dyes by metal hydroxide sludge; effect of temperature, pH and electrolytes", Journal of Colloid and Interface Science, vol.270, pp. 255 – 261, 2004.

.Hesas RH,.Niya AA, Wan Dand WA, Satiu JN, “Preparation and Characterization of Activated Carbon from Apple Waste by Microwave – Assisted Phosphoric acid activation: Application in Methylene Blue Adsorptionâ€, Bioresources, vol.8, no.2, pp. 2950 – 2966, 2013.

Aksu Z, “Application of biosorption for the removal of organic pollutants: A review.†Process Biochemistry, vol.40, pp. 997 – 1026, 2005.

Crini G, “Non – conventional low – cost adsorbents for dye removal: A reviewâ€, Bioresource Technology, vol.60 pp. 67 – 75, 2006.

Forgacs E, Cserhà ti T, Oros G, “Removal of synthetic dyes from wastewaters. A Reviewâ€, Environmental International, vol.30 pp. 953 – 971, 2004.

Qu JH, “Research progress of novel adsorption processes in water purification. A review.†J. of Environmental Sciences, vol 20(1), (2008) 1 – 13.

Bello OS, Ahmad MA, Ahmad N," Adsorptive features of banana (Musa paradisiacal) stalk – based activated carbon for malachite green dye removal, Chem. Ecol., vol.28 ,pp. 153 – 167, 2012.

Bello OS,.Fatona TA, Falaye FS, Oscuolale OM, Njoku VO, " Adsorption of eosin dye from aqueous solution using groundnut hull – based activated carbon: Kinetic, equilibrium and thermodynamic studies", Environ. Eng. Sci., vol.29, pp. 186 – 194, 2012.

Bello OS, Ahmad MA, " Adsorption of dyes from aqueous solution using chemical activated mango peels, In: Preceedings of the 2nd International Conference on Environmental Science and Technology (ICEST), vol.2, pp. 108 – 113, 2011.

Rahman IA, Saad B, Shaidan S, .Sya ES, Riza EL, "Adsorption characteristics of malachite green on activated carbon derived from rice husks produced by chemical – thermal process", Bioresource Technol., vol.14 ,pp. 1578 – 1583,2005.

Hameed BH, “Evaluation of papaya seeds as a novel non – conventional low – cost adsorbent for removal of methylene blueâ€, J. of Hazard. Mater.,vol. 162,pp. 939 – 944, 2009.

Pavan FA, Lima EC,.Dias SP, .MazzocatoAC, “ Methylene blue biosorption from aqueous solution by yellow passion fruit wasteâ€, J. of Hazard. Mater., vol.150, pp. 703 – 712, 2008.

.Mohamed Salleh MA, Mahmoud DK, Abdul Karim WW, Idris A, " Cationic and Anionic dye adsorption by Agricultural Solid Wastes: A comprehensive review, Desalination, vol.280,pp. 1 – 13, 2011.

Patel S, “Potential of fruit and vegetable wastes as novel biosorbents: summarizing the recent studiesâ€, Environ.Sci.Biotechnol., vol.11,pp. 365 – 380, 2012.

Moghadam MR, .Nasirizadeh N, Dashti Z, Babanezhad E., “Removal of Fe (II) from aqueous solution using pomegranate peel carbon: equilibrium and kinetic studiesâ€, International Journal of Industrial Chemistry, vol.4 pp. 19, 2013.

El – Nemr A, “Potential of pomegranate peel carbon for Cr (VI) removal from wastewater: kinetic and isotherm studies, J. of Hazard. Mater., vol.161, pp. 132 – 141, 2009.

Bhatnagar A, Minocha AK, "Biosorption optimization of nickel removal from water using Punica Granatum peel wasteâ€, Colloid Surface B, vol.76, pp. 544 – 548, 2010.

Ghaedi M, Tavallali H, Sharifi M, .Nasiri SK, Asghari A, “ Preparation of low cost activated carbon from Myrtus Communis and pomegranate and their efficient application for removal of Congo Red from aqueous solutionâ€, Spectrochim. Acta Part A, vol.86, pp.104 – 114, 2012.

.Ali HA, Egzar HK, Kamal NM, Sahed NA, Mashkour MS, “Removal of Amaranth Dye from aqueous solution using pomegranate peelâ€, Int. Journal of Basic and Applied Science IJBAS – IJENS, vol.13,pp. 57 – 64, 2013.

Wan Nik WB, Rahman MM, Yusof AM, An FNi, .Che Adnan CM, “ Production of activated carbon fom Palm Oil Shell Waste and its Adsorption Characteristics, Proceedings of the 1st International Conference on Natural Resourcesâ€, Engineering and Technology, 24 – 25th July, Putrtajaya, Malaysia, pp. 646 – 654, 2006.

Girgis BS, Attia AA, .Fathy NA, “ Modification in adsorption characteristics of activated carbon produced by H3PO4 under flowing gasesâ€, Colloid Surface A.Physicochem Eng. Aspect, vol.299, pp. 79 – 87, 2007.

Girgis BS, Smith E, Louis MM, El – Hendawy ANA, “Pilot production of activated carbon from cotton stalks using H3PO4â€, Journal of analytical and pyrolysis, vol. 68(1), pp. 180 – 184, 2009.

Zvezdelina LY, NedyalkaVG, "Insights into Congo Red Adsorption on Agro – Industrial Materials – Spectral, Eqilibrium, Kinetic, Thermodynamic, Dynamic and Desorption Studies. A Reviewâ€, International Review of Chemical Engineering (I.RE.CH.E.), vol.4 (2), pp. 127 – 146, 2012.

Pan X, Zhang D, “Removal of malachite green from water by Firmiana simplex wood fiberâ€, Electronic Journal of Biotechnology, vol.12, pp. 1 – 10, 2009.

Alberghina G, Bianchini R, Fichera M, Fisichella S, “Dimerization of Cibacron Blue F3GA and other dyes: influence of salts and temperature, Dyes and Pigments, vol.46, pp. 129 – 137, 2000.

Germán – Heins J, Flurry M, “Sorption of Brilliant Blue FCF in soils as affected by pH and ionic strengthâ€, Geoderma, vol.97, pp. 87 – 101, 2000.

Ghaedi M, Tavallali H, Sharifi M, Kokhdan SN, Asghari A, “Preparation of low cost activated carbon from Myrtus Communis and pomegranate and their efficient application for removal of Congo Red from aqueous solutionâ€, Spectrochimica Acta, Part A, vol.86, pp. 107 – 114, 2012.

Langmuir I, “The adsorption of gases on plane surface of glass, mica, and platinumâ€, J.Am.Chem.Soc., vol.40 pp. 1361, 1918..

Crini G, “Kinetic and equilibrium studies on the removal of cationic dyes from aqueous solution by adsorption onto a cyclodextrin polymerâ€, Dyes and Pigments, vol.77 (2), pp. 415 – 426, 2008.

.Freundlich HMF, “Über die adsorption in lösungen, Zeit, Phys.Chem.(Leipzig), vol.57 A, pp. 385 – 470, 1906.

Temkin MJ, Pyzhev V, “Recent modification to Langmuir isothermsâ€, Acta Physiochim, USSR, vol.12, pp. 217 – 222, 1940.

Dubinin MM, Radushkevich LV, “Equation of the characteristic curve of activated charcoalâ€, Chem. Zentr.,vol. 1 (1), pp. 875 – 890, 1947.

Vargas AM, Cazetta AL, Kunita MH, Silva TL, Almeida VC, “Adsorption of methylene blue onto activated carbon produced from flamboyant pods ( Delonix vegia) : study of adsorption isotherms and kinetic models, Chem. Eng .Journal, vol.168, pp. 722 – 730, 2011.

Nidheesh PV, Gandhimathi R, Ramesh ST, Ananthasingh TS, “Kinetic analysis of crystal violet adsorption onto bottom ash, Turkish J. Eng. Env. Sci., vol.36, pp. 249 – 262, 2012.

Lagergren S, “Zur theorie der sogenennten adsorption geloster stoffe, Kungliga, Svenska Ventenskademiens, Handlingar, vol.24, pp. 1 – 39, 1898.

Mckay G, Ho YS, “Pseudo – second – order model for sorption processesâ€, Process Biochem., vol.34, pp. 451 – 465, 1999.

Chein SH, Clayton WR, “Application of Elovich equation to the kinetics of phosphate release and sorption on soilsâ€, Soil Sci. Am. J, vol.44, pp. 265 – 268, 1980.

Aharoni C, Sideman S, Hoffer E, “Adsorption of phosphate ions by collodion – coated aluminaâ€, Journal of Chemical Technology and Biotechnology, vol. 29 (7), pp. 404 – 412, 1979.

Tütem E., Apak R., Unal CF, “Adsorptive removal of chlorophenols from water by Bituminous Shaleâ€, Water Research, vol. 32 (8), pp. 2315 – 2324, 1998.

Tan IAW, Ahmad AL, Hameed BH, “Enhancement of basic dye adsorption uptake from aqueous solutions using chemically modified oil palm shell activated carbonsâ€, Colloids and Surface A: Physicochem. Aspects, vol.318, pp. 88 – 96, 2008.

Ahmad R, Kumar R, “Adsorptive removal of congo red dye from aqueous solution using bael shell carbon, Appl.Surf.Sci, vol.257,pp. 1628 – 1633, 2010.

Jnr MH, Spiff AI, “Effect of temperature on the sorption of Pb2+ and Cd2+ from aqueous solution by caladium bicolor (wild cocoyam) biomassâ€, Electronic Journal Biotechnology, vol. 8, pp. 162 – 169, 2005.

Amin NK, “Removal of direct blue – 106 dye from aqueous solution using new activated carbons developed from pomegranate peel: Adsorption equilibrium and kinetics, J. of Hazard. Mater., vol.165, pp. 52 – 62, 2009.

Kaur S, Rani S, .Mahajan RK, “Adsorption kinetics for the removal of hazardous dye Congo Red by biowaste materials as adsorbents, Journal of Chemistry, Article ID 628582, pp. 1 – 12, 2012.

Arivoli S, Kalpana K, Sudha R, Rajachandrasekar T, “Comparative study on the adsorption kinetics and thermodynamics of metal ions onto acid activated low cost carbonâ€, Electronic J.Chem., vol.4, pp. 238 – 254, 2007.

Amin NK, “Removal of direct blue – 106 dye from aqueous solution using new activated carbons developed from pomegranate peel: Adsorption equilibrium and kinetics†J. of Hazard. Mater., vol.165 ( 1 – 3 ) pp. 132 – 141, 2009.

Han R, Zou W, Yu W, Cheng S, Wang Y, Shi J, “Biosorption of methylene blue from aqueous solution by fallen phoenix tree’s leavesâ€, J. of Hazard. Mater., vol.141, pp. 156 – 162, 2007.

Kannan K, Sundaram MM, “Kinetics and mechanism of removal of methylene blue by adsorption on various carbons – a comparative studyâ€, Dyes and Pigments, vol.51, pp. 25 – 40, 2001.

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Published

2015-08-17

How to Cite

Shouman, M. A. H., & Khedr, S. A. A. (2015). Removal of Cationic Dye from Aqueous Solutions by Modified Acid - Treated Pomegranate Peels (PUNICA GRANATUM): Equilibrium and Kinetic Studies. Asian Journal of Applied Sciences, 3(4). Retrieved from https://www.ajouronline.com/index.php/AJAS/article/view/2879

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Vol. 3 No. 4 (2015): August 2015

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